Name: Iron Sulfide Powder
CAS: 1317-37-9
EC Number: 215-268-6
Chemical Formular: FeS
Appearance: Gray powder
Molecular Weight: 87.91 g/mol
Melting Point: 1,194 °C (2,181 °F; 1,467 K)
Boiling Point: n/a
Density: 4.84 g/cm3
Solubility in water: negligible
Exact Mass: 87.907007 g/mol
Monoisotopic Mass: 87.907007 g/mol
Topological Polar Surface Area: 32.1 A^2
Complexity: 2

Iron Sulfide Powder
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Iron Sulfide Powder,customized specifications
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MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Sep 22, 2020

Revision Date: Sep 22, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Iron Sulfide Powder


1.2

Other means of identification

Product number

Other names

Iron(II) sulfide,-100 mesh;Ferrous sulfide;Iron(II) sulfide


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Not classified.


2.2

GHS label elements, including precautionary statements

Pictogram(s)No symbol.
Signal word

No signal word

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Iron Sulfide Powder1317-37-9215-268-6

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.


4.2

Most important symptoms/effects, acute and delayed

no data available


4.3

Indication of immediate medical attention and special treatment needed, if necessary

Maintain an open airway and assist ventilation if necessary. Treat shock caused by hemorrhagic gastrointestinitis aggressively with intravenous crystalloid fluids, and replace blood if needed. Patients are often markedly hypovolemic owing to gastrointestinal losses and third spacing of fluids into the intestinal wall and interstitial space. Treat coma, seizures, and metabolic acidosis if they occur. For seriously intoxicated victims (eg, shock, severe acidosis, and/or serum iron > 500-600 mcg/dL) administer deferoxamine. Monitor the urine for the urine for the characteristic orange or pink deferoxamine-iron complex. Therapy may be stopped when the urine returns to normal or when the serum iron level decreases to the normal range. Prolonged deferoxamine has been associated with adult respiratory distress syndrome and Yersinia sepsis.

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.


5.2

Specific hazards arising from the chemical

no data available


5.3

Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

ComponentIron sulphide
CAS No.1317-37-9

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Iron salts (soluble, as Fe)/

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Solid. Powder.

Colour

Dark brown.

Odour

no data available

Melting point/freezing point

> 1 109 – < 1 150 °C. Remarks:Decomposition and/or sublimation was observed.

Boiling point or initial boiling point and boiling range

Deomposes

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

no data available

Auto-ignition temperature

313.6 °C. Remarks:The air pressure was not provided but since it was explicidly mentioned that it was changed, it can be assumed that the test was performed as normal air pressure.

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

0.00062 G/100 CC WATER AT 18 DEG C; INSOL IN NITRIC ACID; SOL IN ACIDS WITH EVOLUTION OF HYDROGEN SULFIDE

Partition coefficient n-octanol/water

no data available

Vapour pressure

no data available

Density and/or relative density

4.556 g/cm³. Temperature:20 °C.

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

no data available


10.2

Chemical stability

Oxidized by moist air to sulfur and iron oxide.


10.3

Possibility of hazardous reactions

Ferrous sulfide/ is occasionally formed unintentionally when materials containing sulfur are treated in iron and steel vessels- eg in petroleum refineries. If the plant is opened and the deposit of ferrous sulfide is exposed to air, its exothermic oxidation may raise temp of gases and vapors in the vicinity. A fine water spray should be directed on such deposits until flammable vapors have been removed by purging. Similar problems may occur in pyrite mines where the air temperature is increased by a continuous slow oxidation of ore.


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

The use of steel equipment in conjunction with hydrogen sulfide or volatile sulfide compounds will cause it to spontaneously explode in air.


10.6

Hazardous decomposition products

When heated to decomposition it emits toxic fumes of /sulfur oxides/.

SECTION 11: Toxicological information

Acute toxicity

  • Oral: LD50 – rat (female) – > 2 000 mg/kg bw.
  • Inhalation: no data available
  • Dermal: LD50 – rat (male/female) – > 2 000 mg/kg bw.

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: LC50 – > 10 000 mg/L – 96 h.
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Iron Sulfide Powder1317-37-9215-268-6
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Not Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateSep 22, 2020
Revision DateSep 22, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:FeS
PubChem CID:14828
IUPAC Name:sulfanylideneiron
Inchl:InChI=1S/Fe.S
InChI Key:MBMLMWLHJBBADN-UHFFFAOYSA-N
Canonical SMILES:S=[Fe]
Pictogram(s):n/a
Signal:n/a
GHS Hazard Statements:n/a
Hazard Codes:n/a
Risk Codes:n/a
Precautionary Statement Codes:n/a
Flash Point:n/a

Ferrous sulfide
Ferrous sulphide
Iron(II) sulphide
black iron sulfide
thioxiron
Iron monosulfide

iron(2+) sulfide
Troilite
sulfanylideneiron
Iron sulfuret
Iron protosulfide

SulfurSulfur (in non-scientific British use also sulphur) is a chemical element with the symbol S and atomic number 16.
It is abundant, multivalent, and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8.
Elemental sulfur is a bright yellow, crystalline solid at room temperature.
Sulfur burns with a blue flame with formation of sulfur dioxide, which has a suffocating and irritating odor.
Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene.

IronIron is an element with atomic symbol Fe, atomic number 26, and atomic weight 55.85.
It is a metal, that belongs to the first transition series and group 8 of the periodic table. It is by mass the most common element on Earth, forming much of Earth’s outer and inner core. It is the fourth most common element in the Earth’s crust.
Iron is an essential heavy metal that is included in many over-the-counter multivitamin and mineral supplements and is used therapeutically in higher doses to treat or prevent iron deficiency anemia.
When taken at the usual recommended daily allowance or in replacement doses, iron has little or no adverse effect on the liver. In high doses and in intentional or accidental overdoses, iron causes serious toxicities, one component of which is acute liver damage.

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