Name: Lead Sulfide Wafer
CAS: 1314-87-0
EC Number: 215-246-6
Chemical Formular: PbS
Appearance: Black
Molecular Weight: 239.26 g/mol
Melting Point: 1,118 °C (2,044 °F; 1,391 K)
Boiling Point: 1,281 °C (2,338 °F; 1,554 K)
Density: 7.60 g/cm3
Solubility in water: 2.6×10-11 kg/kg
Exact Mass: 239.949 g/mol
Monoisotopic Mass: 239.949 g/mol
Topological Polar Surface Area: 32.1 A^2
Complexity: 2

Lead Sulfide Wafer
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Lead Sulfide Wafer,customized specifications
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MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Sep 30, 2020

Revision Date: Sep 30, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Lead Sulfide Wafer


1.2

Other means of identification

Product number

Other names


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Acute toxicity – Category 4, Oral

Acute toxicity – Category 4, Inhalation

Reproductive toxicity, Category 1A

Specific target organ toxicity – repeated exposure, Category 2

Hazardous to the aquatic environment, short-term (Acute) – Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) – Category Chronic 1


2.2

GHS label elements, including precautionary statements

Pictogram(s)

Signal word

Danger

Hazard statement(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

H360 May damage fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P264 Wash … thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P203 Obtain, read and follow all safety instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

Response

P301+P317 IF SWALLOWED: Get medical help.

P330 Rinse mouth.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P317 Get medical help.

P318 IF exposed or concerned, get medical advice.

P319 Get medical help if you feel unwell.

P391 Collect spillage.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Lead Sulfide Wafer1314-87-0215-246-6

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.


4.2

Most important symptoms/effects, acute and delayed

INHALATION OR INGESTION: Abdominal pain, loss of appetite, weight loss, constipation, apathy or irritability, vomiting, fatigue, headache, weakness metallic taste and muscle incoordination. Lead line on gums. EYES: Irritation. May cause corneal destruction. SKIN: Pain and severe burns. (USCG, 1999)


4.3

Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Lead and Related Compounds

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.


5.2

Specific hazards arising from the chemical

Behavior in Fire: At fire temperatures emits highly toxic and irritating sulfur oxides. (USCG, 1999)


5.3

Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

ComponentLead sulphide
CAS No.1314-87-0

NIOSH considers “Lead” to mean metallic lead, lead oxides, and lead salts (including organic salts such as lead soaps but excluding lead arsenate).

Recommended Exposure Limit: 10 hr Time-Weighted Avg: 0.050 mg/cu m /Lead/

Air concentrations should be maintained so that worker blood lead remains less than 0.06 mg Pb/100 g of whole blood. /Lead/

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Lead sulfide is a black to silvery powdery or crystalline solid. Sinks in water. (USCG, 1999)

Colour

Silvery, metallic crystals or black powder

Odour

no data available

Melting point/freezing point

1114ºC

Boiling point or initial boiling point and boiling range

1281ºC

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

no data available

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

0.01244 g/100 mL water at 20 deg C

Partition coefficient n-octanol/water

no data available

Vapour pressure

1 Pa at 656 deg C; 10 Pa at 741 deg C; 100 Pa at 838 deg C; 1kPa at 953 deg C; 10 kPa at 1088 deg C; 100 kPa at 1280 deg C

Density and/or relative density

7.5g/mLat 25°C(lit.)

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

no data available


10.2

Chemical stability

Stable under recommended storage conditions.


10.3

Possibility of hazardous reactions

The reaction between iodine monochloride and any of the following is vigorous: cadmium sulfide, lead sulfide, silver sulfide, or zinc sulfide [Mellor 2, Supp. 1:502. 1956].


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

Incompatible materials: Strong oxidizing agents, iodine monochloride, hydrogen peroxide


10.6

Hazardous decomposition products

When heated to decomposition it emits very toxic fumes of lead and sulfur oxides.

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

There is limited evidence in humans for the carcinogenicity of inorganic lead compounds. … There is sufficient evidence in experimental animals for the carcinogenicity of inorganic lead compounds. There is sufficient evidence in experimental animals for the carcinogenicity of lead acetate, lead subacetate, lead chromate, and lead phosphate. There is inadequate evidence in experimental animals for the carcinogenicity of lead oxide and lead arsenate. … There is inadequate evidence in experimental animals for the carcinogenicity of lead powder. Overall evaluation Inorganic lead compounds are probably carcinogenic to humans (Group 2A). Inorganic lead compounds

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: LC50; Species: Pimephales promelas (Fathead minnow) age <24 hr, neonate; Conditions: freshwater, static, pH 7.5-9.1, dissolved oxygen saturated; Concentration: 403000 ug/L for 96 hr /total Pb ion
  • Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water Flea) age <24 hr neonate; Conditions: freshwater, static, pH 7.5-9.1, hardness 246-255 mg/L CaCO3, alkalinity 191-202 mg/L CaCO3; Concentration: 9958000 ug/L for 48 hr /total Pb ion
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: UN3077 (For reference only, please check.)IMDG: UN3077 (For reference only, please check.)IATA: UN3077 (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: 9 (For reference only, please check.)IMDG: 9 (For reference only, please check.)IATA: 9 (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: III (For reference only, please check.)IMDG: III (For reference only, please check.)IATA: III (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: YesIMDG: YesIATA: Yes


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Lead Sulfide Wafer1314-87-0215-246-6
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Not Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryNot Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateSep 30, 2020
Revision DateSep 30, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:PbS
PubChem CID:14819
IUPAC Name:sulfanylidenelead
Inchl:InChI=1S/Pb.S
InChI Key:XCAUINMIESBTBL-UHFFFAOYSA-N
Canonical SMILES:S=[Pb]
Pictogram(s):Globally Harmonized System of ClassificationGlobally Harmonized System of ClassificationGlobally Harmonized System of Classification
Signal:Danger
GHS Hazard Statements:H302 + H332-H360Df-H373-H410
Hazard Codes:T,N
Risk Codes:R20/22;R33;R61;R62
Precautionary Statement Codes:P201-P260-P280-P301 + P312 + P330-P308 + P313
Flash Point:n/a

Lead(II) sulfide
Thioxo-λ2-plumbane
Lead monosulfide
Natural lead sulfide
Galena
Plumbous sulfide
thioxo-lambda~2~-plumbane

sulfanylidenelead
Lead(2+) sulfide
Lead sulphide
Natural galena
Lead (II) sulfide (99.999% Pb) black powder
thioxolead
sulfanylidene lead

LeadLead (/ˈlɛd/) is a chemical element with the symbol Pb (from the Latin plumbum) and atomic number 82.
It is a heavy metal that is denser than most common materials.
Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is silvery with a hint of blue; it tarnishes to a dull gray color when exposed to air.
Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements.

SulfurSulfur (in non-scientific British use also sulphur) is a chemical element with the symbol S and atomic number 16.
It is abundant, multivalent, and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8.
Elemental sulfur is a bright yellow, crystalline solid at room temperature.
Sulfur burns with a blue flame with formation of sulfur dioxide, which has a suffocating and irritating odor.
Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene.

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