Name: Phosphorus Bromide
CAS: 7789-60-8
EC Number: 232-178-2
Chemical Formular: Br3P
Appearance: clear, colourless liquid
Molecular Weight: 270.686 g/mol
Melting Point: -41.5 °C (-42.7 °F; 231.7 K)
Boiling Point: 173.2 °C (343.8 °F; 446.3 K)
Density: 2.852 g/cm3
Solubility in water: rapid hydrolysis
Exact Mass: 269.727 g/mol
Monoisotopic Mass: 269.727 g/mol
Topological Polar Surface Area: 0 A^2
Complexity: 8

Phosphorus Bromide
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Phosphorus Bromide,customized specifications
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MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Sep 28, 2020

Revision Date: Sep 28, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Phosphorus Bromide


1.2

Other means of identification

Product number

Other names

phosphorus tribromide;


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Skin corrosion, Sub-category 1B

Specific target organ toxicity – single exposure, Category 3


2.2

GHS label elements, including precautionary statements

Pictogram(s)

Signal word

Danger

Hazard statement(s)

H314 Causes severe skin burns and eye damage

H335 May cause respiratory irritation

Precautionary statement(s)
Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P316 Get emergency medical help immediately.

P321 Specific treatment (see … on this label).

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P319 Get medical help if you feel unwell.

Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Phosphorus BromidePhosphorus tribromide7789-60-8232-178-2

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.


4.2

Most important symptoms/effects, acute and delayed

Inhalation causes severe irritation of nose, throat, and lungs. Ingestion causes burns of mouth and stomach. Contact with eyes or skin causes severe burns. (USCG, 1999)


4.3

Indication of immediate medical attention and special treatment needed, if necessary

Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Cover skin burns with dry sterile dressings after decontamination . Bromine, methyl bromide, and related compounds

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Use water spray to knock down acid vapors.


5.2

Specific hazards arising from the chemical

Special Hazards of Combustion Products: Irritating hydrogen bromide and phosphoric acid vapors may form in fire. Behavior in Fire: Acids formed by reaction with water will attack metals and generate flammable hydrogen gas, which may form explosive mixtures in enclosed spaces. (USCG, 1999)


5.3

Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

Isolate the area until the release is under full control. Use water spray to cool and disperse vapors and protect personnel.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Store in a cool, dry, well-ventilated location. Separate from acids, alkalies, organics, alkali metals.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Phosphorus tribromide is a colorless fuming liquid with a pungent odor. Corrosive to metals and tissue. Boiling point 347°F (175°C). Freezing point -40°F (-40°C).

Colour

Fuming colorless liquid

Odour

Penetrating odor

Melting point/freezing point

-42°C(lit.)

Boiling point or initial boiling point and boiling range

175°C(lit.)

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

125°C(lit.)

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

Reacts with water, ethanol; soluble in acetone, carbon disulfide

Partition coefficient n-octanol/water

no data available

Vapour pressure

0.27 psi ( 54 °C)

Density and/or relative density

2.88g/mLat 20°C(lit.)

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

Fumes in air. Decomposed by water to form phosphorous acid and hydrobromic acid. Reaction with warm water is very rapid and may be violent [Mellor v.8. 1032 1940]. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Bromide gas will be created in 11 minutes. Experimental details are in the following: “Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook”, ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.


10.2

Chemical stability

no data available


10.3

Possibility of hazardous reactions

Not combustible, but if involved in a fire decomposes to produce hydrogen bromide, phosphoric acid, phosphine.PHOSPHORUS TRIBROMIDE reacts with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive; the reactions may be violent. Forms complexes with potassium or sodium metal that explode when shocked. Dropwise addition to 3-phenylpropanol caused an explosion when stirring of the mixture was discontinued [Chem. Brit., 1974, 10, 101-102].


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

Will react with water, steam or acids to produce heat, toxic and corrosive fumes.


10.6

Hazardous decomposition products

If involved in a fire, /phosphorus tribromide/ decomposes to produce hydrogen bromide, phosphoric acid, phosphine.

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: EC50 Daphnia magna at 22.6 mg/L (6.25 mg/L NOEC) for 48 hr.
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: UN1808 (For reference only, please check.)IMDG: UN1808 (For reference only, please check.)IATA: UN1808 (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: PHOSPHORUS TRIBROMIDE (For reference only, please check.)IMDG: PHOSPHORUS TRIBROMIDE (For reference only, please check.)IATA: PHOSPHORUS TRIBROMIDE (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: 8 (For reference only, please check.)IMDG: 8 (For reference only, please check.)IATA: 8 (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: II (For reference only, please check.)IMDG: II (For reference only, please check.)IATA: II (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Phosphorus BromidePhosphorus tribromide7789-60-8232-178-2
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateSep 28, 2020
Revision DateSep 28, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:Br3P
PubChem CID:24614
IUPAC Name:tribromophosphane
Inchl:InChI=1S/Br3P/c1-4(2)3
InChI Key:IPNPIHIZVLFAFP-UHFFFAOYSA-N
Canonical SMILES:P(Br)(Br)Br
Pictogram(s):Globally Harmonized System of ClassificationGlobally Harmonized System of Classification
Signal:Danger
GHS Hazard Statements:H314-H335
Hazard Codes:C
Risk Codes:R14-34-37
Precautionary Statement Codes:P261-P280-P305+P351+P338-P310
Flash Point:n/a

Phosphorus tribromide
Tribromophosphine
Phosphorus(III) bromide
tribromophosphane

PhosphorusPhosphorus is a chemical element with the symbol P and atomic number 15.
Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth.
It has a concentration in the Earth’s crust of about one gram per kilogram (compare copper at about 0.06 grams). With few exceptions, minerals containing phosphorus are in the maximally oxidized state as inorganic phosphate rocks.

BromineBromine is a chemical element with symbol Br and atomic number 35.
It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas.
Its properties are thus intermediate between those of chlorine and iodine.
Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος (“stench”), referencing its sharp and disagreeable smell.

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