Name: Sodium Aluminate
CAS: 1302-42-7
EC Number: 215-100-1
Chemical Formular: NaAlO2
Appearance: white powder
Molecular Weight: 81.969 g/mol
Melting Point: 1,650 °C (3,000 °F; 1,920 K)
Boiling Point: n/a
Density: 1.5 g/cm3
Solubility in water: highly soluble
Exact Mass: 81.961 g/mol
Monoisotopic Mass: 81.961 g/mol
Topological Polar Surface Area: 34.1 A^2
Complexity: 18.3

Sodium Aluminate
ProductORDER
99% Sodium Aluminate
PRICING
Sodium Aluminate,customized specifications
PRICING

MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Aug 31, 2020

Revision Date: Aug 31, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Sodium Aluminate


1.2

Other means of identification

Product number

Other names

Amerfloc 2;Dynaflock;Granular clay


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Fillers,Process regulators,Processing aids, specific to petroleum production,Solids separation agents

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Corrosive to metals, Category 1

Skin corrosion, Sub-category 1A

Serious eye damage, Category 1


2.2

GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H290 May be corrosive to metals

H314 Causes severe skin burns and eye damage

Precautionary statement(s)
Prevention

P234 Keep only in original packaging.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Response

P390 Absorb spillage to prevent material damage.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P316 Get emergency medical help immediately.

P321 Specific treatment (see … on this label).

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P317 Get medical help.

Storage

P406 Store in a corrosion resistant/…container with a resistant inner liner.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Sodium AluminateAluminium sodium dioxide1302-42-7215-100-1

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Fresh air, rest. Refer for medical attention.

Following skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth. Do NOT induce vomiting. Refer for medical attention .


4.2

Most important symptoms/effects, acute and delayed

Excerpt from ERG Guide 154 [Substances – Toxic and/or Corrosive (Non-Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)

Material is caustic. Irritates skin, eyes, and gastrointestinal tract, causing redness of skin and eyes, burning sensation of mucous membranes. (USCG, 1999)


4.3

Indication of immediate medical attention and special treatment needed, if necessary

Treatment: to relieve the gi distress /caused by swallowing aluminum salts/… the degree of dehydration & electrolyte loss caused by vomiting & diarrhea must be determined, & corrected by iv infusions of appropriate solutions. aluminum salts

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Excerpt from ERG Guide 154 [Substances – Toxic and/or Corrosive (Non-Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)


5.2

Specific hazards arising from the chemical

Excerpt from ERG Guide 154 [Substances – Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. (ERG, 2016)

Behavior in Fire: Containers may burst when exposed to heat. (USCG, 1999)


5.3

Special protective actions for fire-fighters

In case of fire in the surroundings, use appropriate extinguishing media.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Wash away remainder with plenty of water.


6.2

Environmental precautions

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Wash away remainder with plenty of water.


6.3

Methods and materials for containment and cleaning up

Aq waste solutions containing sodium aluminate are acidified with sulfuric acid & treated with a weakly basic cmpd (ph 7-11) to improve ppt & filterability of aluminum cmpd.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Separated from food and feedstuffs and acids. Dry.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety goggles, face shield or eye protection in combination with breathing protection.

Skin protection

Protective gloves. Protective clothing.

Respiratory protection

Use local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Solid. Granular mass.

Colour

White.

Odour

no data available

Melting point/freezing point

1 650 °C.

Boiling point or initial boiling point and boiling range

239° F at 760 mm Hg (USCG, 1999)

Flammability

Not combustible.

Lower and upper explosion limit/flammability limit

no data available

Flash point

no data available

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

AQ SOLN IS STRONGLY ALKALINE

Kinematic viscosity

dynamic viscosity (in mPa s) = 121. Temperature:20°C.;dynamic viscosity (in mPa s) = 37. Temperature:40°C.

Solubility

SOL IN WATER; INSOL IN ALCOHOL

Partition coefficient n-octanol/water

no data available

Vapour pressure

no data available

Density and/or relative density

2.602 g/cm³. Temperature:20 °C.;2.6. Temperature:20 °C.

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

The solution in water is a strong base. It reacts violently with acid and is corrosive to aluminium, tin and zinc. Reacts with ammonium salts. This generates fire hazard.


10.2

Chemical stability

no data available


10.3

Possibility of hazardous reactions

SODIUM ALUMINATE, [SOLID] dissolves in water to produce a corrosive alkaline solution. Reacts exothermically with acids. Corrosive to metals. Not compatible with copper, tin, zinc, aluminum, acids, phosphorus, or chlorocarbons.


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

no data available


10.6

Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: LC50 – rat (male) – > 1 000 mg/m³ air.
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

A4: Not classifiable as a human carcinogen. Aluminum metal and insoluble compounds

Reproductive toxicity

no data available

STOT-single exposure

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Medical observation is indicated.

STOT-repeated exposure

no data available

Aspiration hazard

Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: EC50 – Salmo trutta – > 100 mg/L – 96 h.
  • Toxicity to daphnia and other aquatic invertebrates: LC50 – Daphnia magna – 720.8 – 787.8 µg/L – 48 h.
  • Toxicity to algae: EC50 – Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) – 1 282 µg/L – 72 h.
  • Toxicity to microorganisms: EC50 – activated sludge of a predominantly domestic sewage – > 100 mg/L – 3 h. Remarks:Respiration rate.


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: UN1819 (For reference only, please check.)IMDG: UN1819 (For reference only, please check.)IATA: UN1819 (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: SODIUM ALUMINATE SOLUTION (For reference only, please check.)IMDG: SODIUM ALUMINATE SOLUTION (For reference only, please check.)IATA: SODIUM ALUMINATE SOLUTION (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: 8 (For reference only, please check.)IMDG: 8 (For reference only, please check.)IATA: 8 (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: II (For reference only, please check.)IMDG: II (For reference only, please check.)IATA: II (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Sodium AluminateAluminium sodium dioxide1302-42-7215-100-1
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateAug 31, 2020
Revision DateAug 31, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/

Other Information

Other UN numbers: 1819 (sodium aluminate, 80% solution): hazard class: 8, pack group: III.Other CAS number: 11138-49-1.

Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:NaAlO2
PubChem CID:14766
IUPAC Name:sodium;dioxoalumanuide
Inchl:InChI=1S/Al.Na.2O/q-1;+1;;
InChI Key:IYJYQHRNMMNLRH-UHFFFAOYSA-N
Canonical SMILES:O=[Al-]=O.[Na+]
Pictogram(s):Globally Harmonized System of Classification
Signal:Danger
GHS Hazard Statements:H314
Hazard Codes:C
Risk Codes:R36/37/38
Precautionary Statement Codes:n/a
Flash Point:n/a

Aluminum sodium oxide
sodium oxido-oxo-alumane
sodium aluminum oxide
sodium aluminate anhydrous
aluminium sodium dioxide

SodiumSodium atom is an alkali metal atom. It has a role as a Saccharomyces cerevisiae metabolite.
A member of the alkali group of metals. It has the atomic symbol Na, atomic number 11, and atomic weight 23.
It is a soft, silvery-white, highly reactive metal. Because it has a single electron in its outer shell, which it readily donates, creating a positively charged ion—the Na+ cation.
Sodium is the sixth most abundant element in the Earth’s crust and exists in numerous minerals such as feldspars, sodalite, and rock salt (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth’s minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.
Sodium is an essential element for all animals and some plants. Sodium ions are the major cation in the extracellular fluid (ECF) and as such are the major contributor to the ECF osmotic pressure and ECF compartment volume.

AluminumAluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13.
It is a silvery-white, soft, non-magnetic and ductile metal in the boron group.
By mass, aluminium makes up about 8% of the Earth’s crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below.
Aluminum powder, coated appears as a light gray or silver powdered metal. Easily ignited; burns with an intense flame.

OxygenOxygen is the chemical element with the symbol O and atomic number 8, meaning its nucleus has 8 protons.
Oxygen is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.
Dioxygen is used in cellular respiration and many major classes of organic molecules in living organisms contain oxygen, such as proteins, nucleic acids, carbohydrates, and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone.
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774.

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