Name: Titanium Tetrachloride
CAS: 7550-45-0
EC Number: 231-441-9
Chemical Formular: TiCl4
Appearance: Colourless liquid
Molecular Weight: 189.7 g/mol
Melting Point: -24.1 °C (-11.4 °F; 249.1 K)
Boiling Point: 136.4 °C (277.5 °F; 409.5 K)
Density: 1.726 g/cm3
Solubility in water: reacts
Exact Mass: 189.820402 g/mol
Monoisotopic Mass: 187.823352 g/mol
Topological Polar Surface Area: 0 A^2
Complexity: 19.1

Titanium Tetrachloride TiCl4
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Titanium Tetrachloride TiCl4,customized specifications
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MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Sep 15, 2020

Revision Date: Sep 15, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Titanium Tetrachloride


1.2

Other means of identification

Product number

Other names

Titanium tetrachloride;


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Skin corrosion, Sub-category 1B


2.2

GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H314 Causes severe skin burns and eye damage

Precautionary statement(s)
Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P316 Get emergency medical help immediately.

P321 Specific treatment (see … on this label).

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Titanium TetrachlorideTitanium tetrachloride7550-45-0231-441-9

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.

Following skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth. Do NOT induce vomiting. Refer for medical attention .


4.2

Most important symptoms/effects, acute and delayed

no data available


4.3

Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.


5.2

Specific hazards arising from the chemical

Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.


5.3

Special protective actions for fire-fighters

In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Ventilation. Do NOT use water. Collect leaking and spilled liquid in sealable acid resistant containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Separated from food and feedstuffs. Dry. Well closed.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear face shield or eye protection in combination with breathing protection.

Skin protection

Protective gloves. Protective clothing.

Respiratory protection

Use ventilation, local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Liquid.

Colour

Colourless to yellow.

Odour

no data available

Melting point/freezing point

-24.1 °C.

Boiling point or initial boiling point and boiling range

136.4 °C. Remarks:Not determinable.

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

8°C

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

dynamic viscosity (in mPa s) = 0.8. Temperature:20°C.

Solubility

In water: < 5 µg/L. Remarks:Not determinable.

Partition coefficient n-octanol/water

no data available

Vapour pressure

12 hPa. Temperature:20 °C. Remarks:Vapour pressure “p” [Torr] can be calculated by following equation : log p = 1.75 logT – 1764.65/T -0.000665 T +2.90055 with p in mmHg (Torr) and T in °C valid between 20 °C and 135 °C.

Density and/or relative density

1.73 g/cm³. Temperature:20 °C.

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

no data available


10.2

Chemical stability

no data available


10.3

Possibility of hazardous reactions

Decomposes on heating. This produces toxic fumes including hydrogen chloride. Reacts violently with water. This produces heat and corrosive fumes including hydrogen chloride (see ICSC 0163). Contact with air generates hydrochloric acid. Attacks many metals in the presence of water.


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

no data available


10.6

Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: LD100 – rat – 464 mg/kg bw.
  • Inhalation: LC50 – rat (male) – 0.46 mg/L air (analytical).
  • Dermal: LD50 – rabbit – 3 160 mg/kg bw.

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.

STOT-repeated exposure

The substance may have effects on the lungs and respiratory tract. This may result in impaired functions.

Aspiration hazard

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: LL50 – Pimephales promelas – > 1 000 mg/L – 96 h. Remarks:”Ti-pure” Titanium dioxide RPS.
  • Toxicity to daphnia and other aquatic invertebrates: NOELR – other aquatic crustacea: Acartia tonsa – >= 10 000 mg/L – 48 h.
  • Toxicity to algae: NOELR – Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) – > 1 mg/L – 72 h.
  • Toxicity to microorganisms: EC50 – activated sludge, domestic – 5.2 pH – 3 h. Remarks:Respiration rate.


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: UN1838 (For reference only, please check.)IMDG: UN1838 (For reference only, please check.)IATA: UN1838 (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: TITANIUM TETRACHLORIDE (For reference only, please check.)IMDG: TITANIUM TETRACHLORIDE (For reference only, please check.)IATA: TITANIUM TETRACHLORIDE (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: 6.1 (For reference only, please check.)IMDG: 6.1 (For reference only, please check.)IATA: 6.1 (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: I (For reference only, please check.)IMDG: I (For reference only, please check.)IATA: I (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Titanium TetrachlorideTitanium tetrachloride7550-45-0231-441-9
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateSep 15, 2020
Revision DateSep 15, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/

Other Information

Reacts violently with fire extinguishing agents such as water.Depending on the degree of exposure, periodic medical examination is suggested.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation are therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.The decomposition products of this substance may cause effects on the environment.

Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:TiCl4
PubChem CID:24193
IUPAC Name:tetrachlorotitanium
Inchl:InChI=1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI Key:XJDNKRIXUMDJCW-UHFFFAOYSA-J
Canonical SMILES:Cl[Ti](Cl)(Cl)Cl
Pictogram(s):Globally Harmonized System of ClassificationGlobally Harmonized System of ClassificationGlobally Harmonized System of Classification
Signal:Danger
GHS Hazard Statements:H314-H330-H370-H372
Hazard Codes:C
Risk Codes:R14-34
Precautionary Statement Codes:P260-P280-P284-P305 + P351 + P338-P310
Flash Point:n/a

Titanium(IV) chloride
TTC Titanium(4+) tetrachloride Tetrachlorotitanium
Titanic chloride

ChlorineThe chloride ion is the anion (negatively charged ion) Cl−.
It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents.
Chloride salts such as sodium chloride are often very soluble in water.It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating fluid in and out of cells. Less frequently, the word chloride may also form part of the “common” name of chemical compounds in which one or more chlorine atoms are covalently bonded.

TitaniumTitanium atom is a titanium group element atom.
A dark-gray, metallic element of widespread distribution but occurring in small amounts with atomic number, 22, atomic weight, 47.867 and symbol, Ti; specific gravity, 4.5; used for fixation of fractures.
Titanium can be alloyed with iron, aluminium, vanadium, and molybdenum, among other elements, to produce strong, lightweight alloys for aerospace (jet engines, missiles, and spacecraft), military, industrial processes (chemicals and petrochemicals, desalination plants, pulp, and paper), automotive, agriculture (farming), medical prostheses, orthopedic implants, dental and endodontic instruments and files, dental implants, sporting goods, jewelry, mobile phones, and other applications.

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