Name: Zirconium Sputtering Target
CAS: 7440-67-7
EC Number: 231-176-9
Chemical Formular: Zr
Appearance: target
Molecular Weight: 91.224 g/mol
Melting Point: 2128 K ​(1855 °C, ​3371 °F)
Boiling Point: 4650 K ​(4377 °C, ​7911 °F)
Density: 6.52 g/cm3
Solubility in water: n/a
Exact Mass: 89.905 g/mol
Monoisotopic Mass: 89.905 g/mol
Topological Polar Surface Area: 0 A^2
Complexity: 0

Zirconium Sputtering Target
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Zirconium Sputtering Target,customized specifications
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MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Oct 28, 2020

Revision Date: Oct 28, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Zirconium Sputtering Target


1.2

Other means of identification

Product number

Other names


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Elements China Limited

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Pyrophoric solids, Category 1

Substances and mixtures, which in contact with water, emit flammable gases, Category 1


2.2

GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H250 Catches fire spontaneously if exposed to air

H260 In contact with water releases flammable gases which may ignite spontaneously

Precautionary statement(s)
Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P222 Do not allow contact with air.

P233 Keep container tightly closed.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

P223 Do not allow contact with water.

P231+P232 Handle and store contents under inert gas/….Protect from moisture.

Response

P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

P370+P378 In case of fire: Use … to extinguish.

Storage

P402+P404 Store in a dry place. Store in a closed container.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Zirconium Sputtering Target7440-67-7231-176-9

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Fresh air, rest.

Following skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap.

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth.


4.2

Most important symptoms/effects, acute and delayed

no data available


4.3

Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.


5.2

Specific hazards arising from the chemical

Combustible. Many reactions may cause fire or explosion. Finely dispersed particles form explosive mixtures in air.


5.3

Special protective actions for fire-fighters

Use dry sand, dry powder.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

See Chemical Dangers.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

TLV: 5 mg/m3, as TWA; 10 mg/m3 as STEL; A4 (not classifiable as a human carcinogen).MAK not established but data are available

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety goggles.

Skin protection

Protective gloves.

Respiratory protection

Use local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Solid.

Colour

White.

Odour

no data available

Melting point/freezing point

Remarks:Test substance does not melt.

Boiling point or initial boiling point and boiling range

4377°C(lit.)

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

no data available

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

In water: 166 g/L. Temperature:10 °C. pH:0.52. Remarks:Without pH adjustment.;169 g/L. Temperature:20 °C. pH:0.48. Remarks:Without pH adjustment.;< 0.4 mg/L. Temperature:10 °C. pH:4.02. Remarks:With pH adjustment to pH 4.

Partition coefficient n-octanol/water

no data available

Vapour pressure

no data available

Density and/or relative density

1.987. Temperature:20 °C.

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

no data available


10.2

Chemical stability

no data available


10.3

Possibility of hazardous reactions

Dust explosion possible if in powder or granular form, mixed with air.Reacts violently with borax and carbon tetrachloride when heated. Reacts explosively with alkali metal hydroxides when heated.


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

no data available


10.6

Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: LD50 – rat (female) – > 300 – < 2 000 mg/kg bw.
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

May cause mechanical irritation to the eyes.

STOT-repeated exposure

Repeated or prolonged inhalation of dust particles may cause effects on the lungs.

Aspiration hazard

A harmful concentration of airborne particles can be reached quickly when dispersed.

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: LL50 – Oncorhynchus mykiss (previous name: Salmo gairdneri) – > 100 mg/L – 96 h. Remarks:Anhydrous form.
  • Toxicity to daphnia and other aquatic invertebrates: EC50 – Daphnia magna – > 100 % v/v saturated solution – 48 h.
  • Toxicity to algae: EC50 – Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) – 80 % v/v saturated solution – 72 h.
  • Toxicity to microorganisms: no data available


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: Not dangerous goods.(For reference only, please check.)IMDG: Not dangerous goods.(For reference only, please check.)IATA: Not dangerous goods.(For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: ZNot dangerous goods. (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Zirconium Sputtering Target7440-67-7231-176-9
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateOct 28, 2020
Revision DateOct 28, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/

Other Information

Other UN numbers: 1358 Zirconium powder; wetted; hazard class 4.1, packaging group II; 1932 Zirconium scrap, hazard class 4.2, packaging group III; 2009 Zirconium, dry, finished metal sheets, wire, strip, hazard class 4.2, packaging group III; 2858 Zirconium, metal sheets, 18-254 microns, hazard class 4.1, packaging group III.Pure Zirconium sponge is pyrophoric and violently explosive when impure.

Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

Chemical Formular:Zr
PubChem CID:23995
IUPAC Name:zirconium
Inchl:InChI=1S/Zr
InChI Key:QCWXUUIWCKQGHC-UHFFFAOYSA-N
Canonical SMILES:[Zr]
Pictogram(s):n/a
Signal:n/a
GHS Hazard Statements:n/a
Hazard Codes:n/a
Risk Codes:n/a
Precautionary Statement Codes:n/a
Flash Point:n/a

Zirconium sputter target

ZirconiumZirconium is a chemical element with symbol Zr and atomic number 40. The name zirconium is taken from the name of the mineral zircon, the most important source of zirconium. The word zircon comes from the Persian word zargun زرگون, meaning “gold-colored”. It is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, three of which are stable. Zirconium compounds have no known biological role.
In powder form, zirconium is highly flammable, but the solid form is much less prone to ignition. Zirconium is highly resistant to corrosion by alkalis, acids, salt water and other agents.
However, it will dissolve in hydrochloric and sulfuric acid, especially when fluorine is present.
Alloys with zinc are magnetic at less than 35 K.

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